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Specticle 20 WSP

Material Safety Data Sheet

SPECTICLE 20 WSP HERBICIDE

MSDS Number: 102000014590
MSDS Version 1.3
Revision Date: 08/19/2010

SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION

Product name
SPECTICLE 20 WSP HERBICIDE
MSDS Number
102000014590
EPA Registration
No. 432-1499

Bayer Environmental Science
2 T.W. Alexander Drive
Research Triangle PK, NC 27709
USA

For MEDICAL, TRANSPORTATION or other EMERGENCY call: 1-800-334-7577 (24 hours/day)
For Product Information call: 1-800-331-2867

SECTION 2. HAZARDS IDENTIFICATION

NOTE: Please refer to Section 11 for detailed toxicological information.

Emergency Overview
Caution! Hazards to humans. Harmful if swallowed or absorbed through skin. Causes eye irritation. Avoid contact with skin, eyes and clothing. Wash thoroughly with soap and water after handling. Remove and wash contaminated clothing before re-use.
Physical State
powder
Odor
weak characteristic
Appearance
beige
Exposure routes
Ingestion, Inhalation, Skin Absorption
Immediate Effects
Eye
Moderate eye irritation. Do not get in eyes.

-Skin := Harmful if absorbed through skin. Avoid contact with skin, eyes and clothing.

Ingestion
Harmful if swallowed. Do not take internally.
Medical Conditions Aggravated by Exposure
No specific medical conditions are known which may be aggravated by exposure to this product.
Potential Environmental Effect
Toxic to fish and aquatic invertebrates. This product may cause adverse effects on non-target plants.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

_Hazardous Component Name _ CAS-No. _Average % by Weight
Indaziflam 950782-86-2 20.00
Lignosulfonic acid, sodium salt, sulfomethylated 68512-34-5 10.00
Alkylaryl sulfonate 91078-64-7 4.00
Titanium dioxide 13463-67-7 0.67

SECTION 4. FIRST AID MEASURES

General
When possible, have the product container or label with you when calling a poison control center or doctor or going for treatment.
Eye
Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a physician or poison control center immediately.
Skin
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Call a physician or poison control center immediately.
Ingestion
Call a physician or poison control center immediately. Rinse out mouth and give water in small sips to drink. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Never give anything by mouth to an unconscious person. Do not leave victim unattended.
Inhalation
Move to fresh air. If person is not breathing, call 911 or an ambulance, then give
artificial respiration, preferably mouth-to-mouth if possible. Call a physician or poison control center immediately.
Notes to physician
Treatment
Treat symptomatically.

SECTION 5. FIRE FIGHTING MEASURES

Fire and Explosion Hazards
Accumulation of fine dust may entail the risk of a dust explosion in the presence of air.
Suitable extinguishing media
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media
High volume water jet
Fire Fighting Instructions
Keep out of smoke. Fight fire from upwind position. Cool closed containers exposed to fire with water spray. Do not allow run-off from fire fighting to enter
drains or water courses. Firefighters should wear NIOSH approved self-contained breathing apparatus
and full protective clothing.
Dust Explosion Class
St1

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions
Remove all sources of ignition. Keep unauthorized people away. Isolate hazard
area. Avoid contact with spilled product or contaminated surfaces.
-
Methods for cleaning up
Avoid dust formation. Sweep up or vacuum up spillage and collect in suitable container for disposal. Clean contaminated floors and objects thoroughly, observing environmental regulations.
Additional advice
Use personal protective equipment. Material can create slippery conditions. Do
not allow to enter soil, waterways or waste water canal.

SECTION 7. HANDLING AND STORAGE

Handling procedures
Handle and open container in a manner as to prevent spillage. Use only in area provided with appropriate exhaust ventilation. Avoid dust formation. Keep away from heat and sources of ignition. Dust may form explosive mixture in air.
Storing Procedures
Store in a cool, dry place and in such a manner as to prevent cross contamination with other crop protection products, fertilizers, food, and feed. Store in original container and out of the reach of children, preferably in a locked storage area.
Work/Hygienic Procedures
Wash hands thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, using the toilet or applying cosmetics. Remove Personal Protective Equipment (PPE) immediately after handling this product. Before removing gloves clean them with soap and water. Remove soiled clothing immediately and clean thoroughly before using again. Wash thoroughly and put on clean clothing.
Min/Max Storage Temperatures
Recommended minimum transport/storage temperature: -20 °C / -4 °F

Recommended maximum transport/storage temperature: 40 °C / 104 °F

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

General Protection
Follow all label instructions. Train employees in safe use of the product.
Follow manufacturer’s instructions for cleaning/maintaining PPE. If no such instructions for washables, use detergent and warm/tepid water.
Eye/Face Protection
Safety glasses with side-shields
Hand protection
Chemical-resistant gloves (barrier laminate, butyl rubber, nitrile rubber or Viton)
Body Protection
Wear long-sleeved shirt and long pants and shoes plus socks.
Respiratory protection
When respirators are required, select NIOSH approved equipment based on
actual or potential airborne concentrations and in accordance with the appropriate regulatory standards and/or industry recommendations.
Exposure Limits
Indaziflam 950782-86-2 OES BCS* TWA 0.14 mg/m3
Kaolin 1332-58-7 ACGIH TWA 2 mg/m3
NIOSH REL 5 mg/m3
NIOSH REL 10 mg/m3
US CA OEL TWA PEL 2 mg/m3
TX ESL ST ESL 20 ug/m3
TX ESL AN ESL 2 ug/m3
TX ESL ST ESL 20 ug/m3
TX ESL AN ESL 2 ug/m3
TWA 10 mg/m3
TWA 5 mg/m3
Synthetic amorphous silica 112926-00-8 OSHA Z1A TWA 6 mg/m3
TX ESL ST ESL 40 ug/m3
TX ESL AN ESL 4 ug/m3
TWA 6 mg/m3
Titanium dioxide 13463-67-7 ACGIH TWA 10 mg/m3
OSHA Z1 PEL 15 mg/m3
OSHA Z1A TWA 10 mg/m3
TX ESL ST ESL 50 ug/m3
TX ESL AN ESL 5 ug/m3
TWA 10 mg/m3

*OES BCS: Internal Bayer CropScience “Occupational Exposure Standard”

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance
beige
Physical State
powder
Odor
weak characteristic
pH
8 – 11 (1 %) at 23 °C
Bulk density
195 – 229 kg/m3
Minimum Ignition Energy
> 0.3 – < 1 J
Decomposition temperature
> 250 °C , Heating rate: 5 K/min
Other information
The product is capable of dust explosions.

SECTION 10. STABILITY AND REACTIVITY

Hazardous reactions
No hazardous reactions when stored and handled according to prescribed
instructions.
Chemical Stability
Stable under recommended storage conditions.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute oral toxicity
male/female combined rat: LD50: > 900 mg/kg
female rat: LD50: > 2,000 mg/kg
Acute dermal toxicity
male/female combined rat: LD50: > 2,000 mg/kg
Acute inhalation toxicity
rat: LC50: > 5.165 mg/l
Exposure time: 4 h
Determined in the form of a respirable fine dust.
highest concentration tested

rat: LC50: > 20.66 mg/l
Exposure time: 1 h
Determined in the form of a respirable fine dust.
Extrapolated from the 4 hr LC50.

Skin irritation
rabbit: No skin irritation
Eye irritation
rabbit: No eye irritation
Sensitisation
Assessment Carcinogenicity
ACGIH
Titanium dioxide 13463-67-7 Group A4
NTP
None.
IARC
Titanium dioxide 13463-67-7 Overall evaluation 2B
OSHA
None.

SECTION 12. ECOLOGICAL INFORMATION

Toxicity to fish
Oncorhynchus mykiss (rainbow trout)
LC50: 0.572 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient.
Toxicity to aquatic plants
Pseudokirchneriella subcapitata
Growth rate
IC50: 0.134 mg/l
Exposure time: 96 h
The value mentioned relates to the active ingredient.
Acute Toxicity to Aquatic Invertebrates
Water flea (Daphnia magna)
EC50: > 9.88 mg/l
Exposure time: 48 h
The value mentioned relates to the active ingredient.
Environmental precautions
Do not apply directly to water, to areas where surface water is present or to intertidal areas below the mean high water mark. Do not contaminate surface or ground water by cleaning equipment or disposal of wastes, including equipment wash water. Do not allow to get into surface water, drains and ground water.

SECTION 13. DISPOSAL CONSIDERATIONS

General Disposal Guidance
Dispose in accordance with all local, state/provincial and federal regulations.
Container Disposal
Follow advice on product label and/or leaflet. Do not re-use empty containers.
Dispose of empty container in a sanitary landfill or by incineration, or, if allowed by State/Provincial and local authorities, by burning. If burned, stay out of smoke.
RCRA Information
Characterization and proper disposal of this material as a special or hazardous
waste is dependent upon Federal, State and local laws and are the user’s responsibility. RCRA classification may apply.

SECTION 14. TRANSPORT INFORMATION

CFR
Not dangerous goods / not hazardous material
IMDG
UN-Number
3077
Class
9
Packaging group
III
Marine pollutant
Marine Pollutant
Description of the goods
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(INDAZIFLAM MIXTURE)
IATA
UN-Number
3077
Class
9
Packaging group
III
Description of the goods
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(INDAZIFLAM MIXTURE )

This transportation information is not intended to convey all specific regulatory information relating to this
product. It does not address regulatory variations due to package size or special transportation requirements.

SECTION 15. REGULATORY INFORMATION

EPA Registration No.
432-1499

US Federal Regulations

TSCA list
Lignosulfonic acid, sodium salt, sulfomethylated 68512-34-5
Titanium dioxide 13463-67-7
US. Toxic Substances Control Act (TSCA) Section 12(b) Export Notification (40 CFR 707, Subpt D)
None.
SARA Title III – Section 302 – Notification and Information
None.
SARA Title III – Section 313 – Toxic Chemical Release Reporting
None.

US States Regulatory Reporting

CA Prop65
This product does not contain any substances known to the State of California to cause cancer.

This product does not contain any substances known to the State of California to cause reproductive
harm.

US State Right-To-Know Ingredients

Titanium dioxide 13463-67-7 IL, MN, RI
None.

Canadian Regulations

Canadian Domestic Substance List
Lignosulfonic acid, sodium salt, sulfomethylated 68512-34-5
Alkylaryl sulfonate 91078-64-7
Titanium dioxide 13463-67-7

Environmental

CERCLA
None.
Clean Water Section 307 Priority Pollutants
None.
Safe Drinking Water Act Maximum Contaminant Levels
None.

International Regulations

European Inventory of Existing Commercial Substances (EINECS)
Titanium dioxide 13463-67-7

SECTION 16. OTHER INFORMATION

NFPA 704 (National Fire Protection Association):
Health – 1 Flammability – 1 Reactivity – 0 Others – none

HMIS (Hazardous Materials Identification System, based on the Third Edition Ratings Guide)
Health – 1 Flammability – 1 Physical Hazard – 0 PPE -

0 = minimal hazard, 1 = slight hazard, 2 = moderate hazard, 3 = severe hazard, 4 = extreme hazard

Reason for Revision: Updated for general editorial purposes. The following sections have been revised:
Section 2: Hazards Identification. Section 14: Transport Information.

Revision Date: 08/19/2010

This information is provided in good faith but without express or implied warranty. The customer assumes all responsibility for safety and use not in accordance with label instructions. The product names are registered trademarks of Bayer.